The Journal of Physical Chemistry

Matrix isolation study of the reaction of diborane with hydrogen sulfide: spectroscopic characterization of mercaptoborane, H2BSH

JD Carpenter, BS Ault

文献索引：Carpenter, John D.; Ault, Bruce S. Journal of Physical Chemistry, 1992 , vol. 96, # 20 p. 7913 - 7916

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被引用次数: 22

摘要

Merged jet copyrolysis of mixtures of Ar/BzH6 and Ar/HzS followed by trapping in a cryogenic matrix has led to the formation, isolation, and characterization of mercaptoborane, H2BSH. Eight of the nine fundamentals of this molecule were observed, including the boron- sulfur stretching mode at 804 cm-l (" B). Local density functional and normal-coordinate calculations were carried out to assist in assigning the observed fundamentals. The ...