Organic letters

On the mechanism of palladium-catalyzed coupling of haloaryls to biaryls in water with zinc

S Mukhopadhyay, G Rothenberg, D Gitis…

文献索引：Organic Letters, , vol. 2, # 2 p. 211 - 214

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被引用次数: 79

摘要

... Organic Letters. ... g (8.4 mol % of 1a); NaOH, 100 mmol; 100 °C; 1 h stirring (2 h for entries 18−28); 50 mL total reaction volume (water, except ... 4). Another possible route for the reduction reaction is direct hydrogen-transfer from water, in the presence of zinc, to the organic substrate ...