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Tetrahedron Letters

H/α-CN versus H/β-CN rate ratios in the solvolysis of sulfonate esters in unconstrained systems. Additional evidence for conjugative stabilization of attached …

PG Gassman, K Saito

文献索引:Gassman, Paul G.; Saito, Katsuhiro Tetrahedron Letters, 1981 , vol. 22, # 14 p. 1311 - 1314

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被引用次数: 11

摘要

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... H/α-CN and H/β-CN rate ratios have been measured for the solvolysis of sulfonate esters of relatively simple, noncyclic aliphatic alcohols. The β-CN function was found to be far more rate retarding than the α-CN function. ... The same problem exists with other systems in which the ...