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The Journal of Organic Chemistry

Heterocyclic Compounds Containing Adjacent Nitro and Guanidino Groups. A Novel Rearrangement of 4-Amino-5-nitro-6-guanidino-(and 6-ureido) pyrimidine

JA CARBON

文献索引:Carbon,J.A. Journal of Organic Chemistry, 1961 , vol. 26, p. 455 - 461

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被引用次数: 9

摘要

FEBRUARY 1961 REARRANGEMENT OF 4-AMINO-5-NITRO-6-GUANJDINO PY RIMIDJNE chloro-5-nitropyrimidine by the guanidine group proceeded normally under the same condi- tions to give a 78% yield of the desired-4amino-6-guanidin0-5-nitropyrimidine (XII), along with a very small quantity of the ether, 4-amino-6-ethoxy-5-nitro-pyrimidine (XIII). The chemistry of this guanidino pyrimidine (XII) has proved to be fairly complex. For example, ...