Stereochemistry of nucleophilic substitution reactions depending upon substituent: evidence for electrostatic stabilization of pseudoaxial conformers of oxocarbenium …

L Ayala, CG Lucero, JAC Romero…

文献索引：Schure, Ralph; Mar, Aye Aye; Pease, Brian; Jones, Wyeth; Felt, Barb; Iyer, Mani S. Organic Process Research and Development, 1999 , vol. 3, # 2 p. 135 - 138

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被引用次数: 176

摘要

... are important reactive intermediates in both bioorganic 1-5 and synthetic organic chemistry. ... In addition to ground-state influences, destabilizing steric interactions that develop in the transition ... Several research groups have noted that their results are consistent with the reactions ...