Total synthesis of viridiofungin A

…, K Takahashi, J Ishihara, S Hatakeyama

文献索引：Morokuma, Kenji; Takahashi, Keisuke; Ishihara, Jun; Hatakeyama, Susumi Chemical Communications, 2005 , # 17 p. 2265 - 2267

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被引用次数: 11

摘要

Viridiofungin A, a member of amino alkyl citrate antibiotics from Trichoderma viride, was enantioselectively synthesized in naturally occurring form for the first time, employing regio- and stereoselective opening of the chiral glycidate with vinylmagnesium bromide and alkene cross metathesis of the citric acid core and hexadec-15-en-8-one as key steps.