Synthesis of α, β-unsaturated carbonyl compounds by successive rearrangement and peterson olefination of β′-hydroxy-α, β-epoxysilanes

F Sato, Y Tanaka, H Kanbara

文献索引：Sato, Fumie; Tanaka, Youichi; Kanbara, Hiroshi Journal of the Chemical Society, Chemical Communications, 1983 , # 18 p. 1024 - 1025

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摘要

Rearrangement reactions of a$-epoxysilanes and 1,2- elimination reactions of P-functionalized organosilanes have been extensively studied and widely applied to organic synthesis.l However, there are few investigations of the chemistry of P'-functionalized x,P-epoxysilanes which contain both an cc,p-epoxysilane and a P-functionalized organosilane skeleton adjoining each other. The only reactions so far ... Table 1. Reaction of complexes (2) with BF3.0Et,.a ...