The Journal of Organic Chemistry

Addition of phenols to perfluorovinyl ethers. Protonation and halogenation of carbanionic intermediates

AE Feiring, ER Wonchoba

文献索引：Feiring, Andrew E.; Wonchoba, Edward R. Journal of Organic Chemistry, 1992 , vol. 57, # 26 p. 7014 - 7017

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被引用次数: 38

摘要

Fluorinated ethers ArOCF2CFHO& are obtained in good yield by base-catalyzed addition of phenols to perfluoroallryl vinyl ethers, CF&FO& (&= C3F7, C3F70CF (CF3) CF2, CH302CCF2CF20CF (CF3) CF2). Reaction of sodium phenoxides with fluorinated vinyl ethers and hexachloroethane affords chlorinated ethers ArOCF&FClO&. Treatment of BrCF2CFBrOC3F7 with sodium phenoxide in the presence of CF2= CFOC3F7 gives ...