Electrochemical synthesis of ketones from acid chlorides and alkyl and aryl halides catalysed by nickel complexes

H Marzouk, Y Rollin, JC Folest, JY Nédélec…

文献索引：Marzouk, H.; Rollin, Y.; Folest, J. C.; Nedelec, J. Y.; Perichon, J. Journal of Organometallic Chemistry, 1989 , vol. 369, p. C47 - C50

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被引用次数: 25

摘要

Abstract The nickel-catalysed electrochemical cross-coupling of acid chlorides and alkyl or aryl halides in acetonitrile affords unsymmetric ketones in good to high yields. The reaction can be performed under very simple and mild conditions in a diaphragmless cell. A zinc rod as the sacrificial anode has been found to be the most efficient.