Polystyrene-bound Mn (T4PyP): A highly efficient and reusable catalyst for biomimetic oxidative decarboxylation of carboxylic acids with sodium periodate
In this report, highly efficient oxidative decarboxylation of carboxylic acids with sodium periodate catalyzed by a supported manganese (III) porphyrin is described. In the presence of manganese (III) tetra (4-pyridyl) porphyrin supported on cross-linked chloromethylated polystyrene,[Mn (T4PyP)-CMP], as catalyst, carboxylic acids were converted to their corresponding carbonyl compounds via oxidative decarboxylation with sodium periodate ...