前往化源商城

The Journal of Organic Chemistry

Cobalt-mediated synthesis of nitro enones from 1, 3-dienes and alkylnitronates

LS Hegedus, RJ Perry

文献索引:Hegedus, Louis S.; Perry, Robert J. Journal of Organic Chemistry, 1984 , vol. 49, # 14 p. 2570 - 2574

全文:HTML全文

被引用次数: 28

摘要

Nitronate anions react with (r-ally1) cobdt complexes produced from the acylation of l, &dienes by acetylcobdt tetracarbonyl to produce nitro enones. With sterically hindered nitronates or (r-ally1) cobalt species, elimination to form the dienone is a competing process. Allenes undergo a similar process.