Synthesis of 2-methylene-1, 3-dioxygenated cyclopentanes and cyclopentenes

…, C Thebtaranonth, Y Thebtaranonth, C Yenjai

文献索引：Chantarasiri, Nuanphun; Dinprasert, Pranee; Thebtaranonth, Chachanat; Thebtaranonth, Yodhathai; Yenjai, Chavi Journal of the Chemical Society, Chemical Communications, 1990 , # 4 p. 286 - 288

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被引用次数: 7

摘要

Anthracene adducts (4)–(6) are synthesized via a convenient general synthesis and subjected to a retro Diels-Alder reaction to furnish the corresponding 2-methylene-1, 3- dioxygenated cyclopentenes and cyclopentanes (1)–(3) via either flash vacuum pyrolysis or room temperature silica gel-catalysed decomposition.