ORGANIC PHOSPHORUS COMPOUNDS 871: SOME REACTIONS OF 0-ETHYL-2-CHLOROETHYLPHOSPHONITE

L Maier, PJ Diel

文献索引：Maier, Ludwig; Diel, Peter J. Phosphorus, Sulfur and Silicon and the Related Elements, 1989 , vol. 45, p. 165 - 176

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被引用次数: 9

摘要

Abstract Primary and secondary amines react with O-ethyl-2-chloroethylphosphonite with the formation of 2-substituted aminoethylphosphonites, RR′ NCH2CH2P (O)(OC2H5) H, 1. The reaction very likely proceeds through the intermediate formation of O-ethyl- vinylphosphonite. Hydrolysis of 1 produces the hydrochlorides of 2-substituted aminoethylphosphonous acids, RR′ NCH2CH2PO2H2 2. These compounds interact ...