Tetrahedron

Palladium (II)-and mercury (II)-catalyzed rearrangements of propargyl acetates

PA Caruana, AJ Frontier

文献索引：Caruana, Patrick A.; Frontier, Alison J. Tetrahedron, 2007 , vol. 63, # 43 p. 10646 - 10656

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被引用次数: 28

摘要

The scope and utility of the metal-catalyzed rearrangement of propargyl acetates first reported by Rautenstrauch were expanded. Treatment of a series of appropriate acetate substrates with Pd (II)-and Hg (II)-catalysts afforded synthetically useful fused 5, 6-bicyclic-1, 4-cyclopentadienyl acetates and 2-cyclopentenones. It was found that the substituents at the terminal alkynyl and alkenyl positions of the acetate substrate had a significant impact on ...