Synthesis and Characterization of Bis (triaminoguanidinium) 5, 5′??Dinitrimino??3, 3′??azo??1H??1, 2, 4??triazolate–A Novel Insensitive Energetic Material
A Dippold, TM Klapötke…
文献索引：Dippold, Alexander; Klapoetke, Thomas M.; Martin, Franz A. Zeitschrift fur Anorganische und Allgemeine Chemie, 2011 , vol. 637, # 9 p. 1181 - 1193
Abstract The synthesis of 5, 5′-diamino-3, 3′-azo-1H-1, 2, 4-triazole (3) by reaction of 5- acetylamino-3-amino-1H-1, 2, 4-triazole (2) with potassium permanganate is described. The application of the very straightforward and efficient acetyl protection of 3, 5-diamino-1H-1, 2, 4-triazole allows selective reactions of the remaining free amino group to form the azo- functionality. Compound 3 is used as starting material for the synthesis of 5, 5′- ...
