Bulletin of the Chemical Society of Japan

Preferential introduction of a pyridylmethyl group into sulfonamides as an approach to an intramolular transimination.

M Iwata, H Kuzuhara

文献索引：Iwata, Masaaki; Kuzuhara, Hiroyoshi Bulletin of the Chemical Society of Japan, 1982 , vol. 55, # 7 p. 2153 - 2157

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被引用次数: 16

摘要

N, N′-Bis (p-tolylsulfonyl)-α-ω-alkanediamine disodium salts (n= 3, 4, 5, 6, 7, 8, 9, 10) were subjected to monopyridylmethylation by the reaction with 5′-deoxy-5′-chloro-or 5′- deoxy-2′-chloro-3, 4′-O-isopropylidenepyridoxine hydrochloride, accompanied by the corresponding bispyridylmethylation. Monopyridylmethylation became remarkable for longer methylene chains of the diamine. Thus, introduction of an amino group protected by a ...