Thermochimica acta

A novel HEMA-derived monomer and copolymers containing side-chain thiophene units: Synthesis, characterization and thermal degradation kinetics

SK Çekingen, F Saltan, Y Yildirim, H Akat

文献索引：Cekingen, Sinem Kadriye; Saltan, Fehmi; Yildirim, Yeliz; Akat, Hakan Thermochimica Acta, 2012 , vol. 546, p. 87 - 93,7

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被引用次数: 4

摘要

In this study, a novel 2-{[2-(3-thienyl) acetyl] oxy} ethyl2-methylacrylate (HEMAT) monomer was synthesized by esterification reaction of 2-hydroxyethyl methacrylate (HEMA) with 3- thiophene acetic acid. Homopolymer and random copolymer of HEMAT and methyl methacrylate (MMA) were prepared by bulk polymerization at 65° C using AIBN as an initiator. The polymers were characterized by FT-IR and 1H NMR. PHEMAT and P (MMA- ...