Tetrahedron letters

Use of 2, 3-(diphenylsulfonyl)-1-propene as an allene equivalent in cycloaddition chemistry

A Padwa, DN Kline, BH Norman

文献索引：Padwa, Albert; Kline, Donald N.; Norman, Bryan H. Tetrahedron Letters, 1988 ,  vol. 29,  # 3  p. 265 - 268

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被引用次数: 22

摘要

... 2; I. Fleming; Frontier Orbitals and Organic Chemical ReactionsJ. Wiley, Inc, N. Y (1976). 3; MDNO calculations indicate that the introduction of a phenylsulfonyl group causes a significant lowering of the LUMO energy level compared with allene and the largest LUMO coefficient resides on the central carbon and the next on the carbon bearing the phenylsulfonyl group. 4; A. Padwa, SP Carter, U. Chiacchio, DN Kline; Tetrahedron Lett. (1986), p. 2683. ...