Temperature dependence of the equilibrium CH2 (OH) 2+ HSO3-= CH2 (OH) SO3-+ H2O in aqueous solution

…, R Neeb, G Helas, P Warneck

文献索引：Deister, U.; Neeb, R.; Helas, G.; Warneck, P. Journal of Physical Chemistry, 1986 , vol. 90, # 14 p. 3213 - 3217

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被引用次数: 73

摘要

Ultraviolet absorption spectrometry was used to measure concentrations of bisulfite in thermal equilibrium with formaldehyde and hydroxymethanesulfonate in deaerated, argon- saturated aqueous solutions. The equilibrium constant of the title reaction was determined as a function of temperature in the range 288-318 K for pH values of 5-6, and at 298 K as a function of pH in the range 4.1-9.7. The temperature dependence (at pH 5-6) is ...