前往化源商城

Kinetics of the reaction of amines with 1, 1, 1??trichloro??4??methoxy??3??penten??2??one

JC Gesser, C Zucco, F Nome

文献索引:Gesser, Jose Carlos; Zucco, Cesar; Nome, Faruk Journal of Physical Organic Chemistry, 1995 , vol. 8, # 2 p. 97 - 102

全文:HTML全文

被引用次数: 7

摘要

Abstract The kinetics of the reaction of 1, 1, 1-trichloro-4-methoxy-3-penten-2-one with various aliphatic and aromatic amines was studied at 25 C in water, dimethyl sulphoxide, methanol, ethanol, chloroform, toluene and hexane. The formation of the corresponding 1, 1, 1-trichloro-4-amino-3-penten-2-one is explained in terms of an addition–elimination mechanism.