Structure and Magnetism of a New Dodecanuclear CuII Complex with Acetato and Imidazolato Bridges, Formed by Oxidation of the Chelating Ligand 1, 1, 7, 7?? …

Y Song, P Gamez, AF Stassen, M Lutz…

文献索引：Song, Yufei; Gamez, Patrick; Stassen, Arno F.; Lutz, Martin; Spek, Anthony L.; Reedijk, Jan European Journal of Inorganic Chemistry, 2003 , # 22 p. 4073 - 4077

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被引用次数: 7

摘要

Abstract A novel dodecanuclear copper (II) complex [Cu 12 (tidhd) 4 (MeOH) 8 (CH 3 COO) 8](MeOH) 0.8 (Htidhd= 1, 1, 7, 7-tetrakis (imidazol-2-yl)-2, 6-diaza-1, 6-heptadiene) with imidazolato and acetato bridging ligands was synthesized by reaction of polyimidazole 1, 1, 7, 7-tetrakis (imidazol-2-yl)-2, 6-diazaheptane (Htidahp) with copper acetate in a methanol solution. The complex crystallized in the triclinic space group P equation image with a= ...