Tetrahedron

Spectroscopic behaviour of methyl chlorooctanoates

J Font, A Moral, F Sánchez-Ferrando, J Elguero

文献索引：Font,J. et al. Tetrahedron, 1978 , vol. 34, p. 791 - 798

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被引用次数: 2

摘要

The synthesis of the seven isomeric methyl chlorooctanoates is reported, in most cases for the first time, and their spectral characteristics are described and studied. Hypotheses are advanced to explain the abnormal spectral behaviour of some of them. The mass spectra show scrambling of hydrogen/chlorine and/or the chain carbons, as well as low ability to undergo the McLafferty rearrangement, in some cases. A complete set of 13C NMR ...