Macromolecules

Synthesis and analysis of telechelic polyisobutylenes for hydrogen-bonded supramolecular pseudo-block copolymers

WH Binder, MJ Kunz, C Kluger, G Hayn, R Saf

文献索引：Binder, Wolfgang H.; Kunz, Michael J.; Kluger, Christian; Hayn, Getraud; Saf, Robert Macromolecules, 2004 , vol. 37, # 5 p. 1749 - 1759

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被引用次数: 112

摘要

New telechelic polyisobutylenes (PIB) with hydrogen-bonding motifs were prepared. Nucleobases such as thymine, uracil, and cytosine as well as chelate-type hydrogen- bonding donor-acceptors were affixed onto the end groups of the PIB. Starting with PIB of defined molecular weight, prepared by living cationic polymerization, hydroxyterminated PIB was generated, which subsequently was transformed into the corresponding chloromethyl ...