Silicon analogs of the thioxanthenes

JY Corey, MJ Dye, RL Farrell, MV Mitchell

文献索引：Corey,J.Y. et al. Journal of Organometallic Chemistry, 1978 , vol. 153, p. 127 - 135

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被引用次数: 18

摘要

Abstract The 9, 10-dihydro-9-silaanthracene framework generated from (o-ClMgC 6 H 4) 2 CH 2 and a dichlorosilane provides the starting point for formation of derivatives which contain a tricyclic skeleton and a three-atom side chain terminated by a nitrogen group bonded to the central ring of the framework. Reaction of the ketone, 10-oxo-9, 9-dimethyl-9, 10-dihydro-9-silaanthracene with either N, Ndimethylaminopropylmagnesium chloride or ...