Metallation of 1, 3??dienyl ethers and 1, 3??dienyl sulfides in the 1??position

RH Everhardus, R Gräfing…

文献索引：Everhardus,R.H. et al. Recueil des Travaux Chimiques des Pays-Bas, 1978 , vol. 97, # 3 p. 69 - 72

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被引用次数: 29

摘要

Abstract 1, 3-Dienyl ethers and the corresponding sulfides (CH 2 [DOUBLE BOND] CH [BOND] CH [DOUBLE BOND] CH [BOND] XR; X [DOUBLE BOND] O, S; R [DOUBLE BOND] alkyl, phenyl) are readily metallated at C-1, using n-butyllithium and KO-t-Bu in tetrahydrofuran. 2H-Thiopyran can be lithiated at the 6-position with n-butyllithium and tetramethylethylenediamine in tetrahydrofuran. The various metallated compounds react ...