Synthesis, Characterisation, and X??ray Crystal Structure of New NiII, PdII, and PtII Complexes of Tridentate Pyrazole??Based Ligands with an NOS??Donor Set

…, J Pons, X Solans, M Font??Bardia, J Ros

文献索引：Garcia-Anton, Jordi; Pons, Josefina; Solans, Xavier; Font-Bardia, Merce; Ros, Josep European Journal of Inorganic Chemistry, 2003 , # 16 p. 2992 - 3000

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被引用次数: 17

摘要

Abstract Treatment of the ligands 1-(3-thia-5-hydroxypentyl)-3, 5dimethylpyrazole (thpd) and 1-(3-thia-6-hydroxyhexyl) 3, 5-dimethylpyrazole (thhd) with [PdCl 2 (CH 3 CN) 2],[PtCl 2 (CH 3 CN) 2], and NiCl 2· 6H 2 O produces the complexes [MCl 2 (L)][M= Pd, L= thpd (1), thhd (2); M= Pt, L= thpd (3), thhd (4); M= Ni, L= thpd (5), thhd (6)], which have been characterised by elemental analyses, conductivity, IR, electronic spectra, and NMR spectroscopy (when ...