Reaction studies on hypervalent silicon hydride compounds

M Weinmann, O Walter, G Huttner, H Lang

文献索引：Weinmann, Markus; Walter, Olaf; Huttner, Gottfried; Lang, Heinrich Journal of Organometallic Chemistry, 1998 , vol. 561, # 1-2 p. 131 - 141

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被引用次数: 23

摘要

The versatile reaction chemistry of penta-coordinated silanes of type [C6H4CH2N (CH3) 2 2](H2C CH)(CH3) SiH (1a) and [C6H4CH2N (CH3) 2 2](H2C CH) SiH2 (1b) with different substrates is described. The reaction behavior along with the structure and bonding of the compounds obtained is compared with tetravalent silicon molecules. Hypervalent 1a and 1b react, without added catalysts, with alcohols, water and benzoylic acid to produce ...