Dalton Transactions

Organochromium complexes as catalysts for the carboalumination of unactivated terminal olefins

S Mark, N Gaidzik, S Doye, M Enders

文献索引：Mark, Stefan; Gaidzik, Nikola; Doye, Sven; Enders, Markus Dalton Transactions, 2009 , # 25 p. 4875 - 4877

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被引用次数: 2

摘要

The addition of aluminium alkyls to terminal olefins leads to branched organoaluminium compounds which can be converted into functionalised alkanes. This carboalumination reaction is efficiently catalysed by a donor functionalised Cp-chromium (III) complex. The active catalyst is obtained by activation of the chromium (III) dichloride precursor with MAO or with a mixture of trialkylaluminium and N, N-dimethylanilinium ...