Excited-state mixed-valence distortions in a diisopropyl diphenyl hydrazine cation
…, MN Weaver, AE Konradsson, JW Fowble…
文献索引：Lockard, Jenny V.; Zink, Jeffrey I.; Luo, Yun; Weaver, Michael N.; Konradsson, Asgeir E.; Fowble, Joseph W.; Nelsen, Stephen F. Journal of the American Chemical Society, 2006 , vol. 128, # 51 p. 16524 - 16531
Excited-state mixed valence (ESMV) occurs in the 1, 2-diphenyl-1, 2-diisopropyl hydrazine radical cation, a molecule in which the ground state has a symmetrical charge distribution localized primarily on the hydrazine, but the phenyl to hydrazine charge-transfer excited state has two interchangeably equivalent phenyl groups that have different formal oxidation states. Electronic absorption and resonance Raman spectra are presented. The ...
