Triple-decker complexes. 8. Triple-decker sandwiches. Syntheses, reactivity, electrochemistry, and x-ray crystal and electronic structures of bis (cyclopentadienylmetal …
J Edwin, M Bochmann, MC Boehm…
文献索引：Edwin,J.; Bochmann,M.; Boehm,M.C. Journal of the American Chemical Society, 1983 , vol. 105, p. 2582
Abstract: The methyltetraethyl and the diethyldimethyl derivatives of the A4-1, 3-diborolene heterocycle CB2H6, 6a, b, were used for the synthesis of the triple-decker series (T&H,) M (~ C, B, H,) M'(~~-C~ H,), with MM'= FeCo, CoCo, CoNi, and NiNi (30-33 valence electrons). This was achieved either by stacking the corresponding derivatives of the sandwich complexes (a5-C5H5) Ni ($-C3B, H,)(13a, b) or ($-C5H5) Co ($-C3B2H6)(18a, b) with the ...
