Photochemical generation of radical anions of photolabile aryl ketones

N Mathivanan, LJ Johnston…

文献索引：Mathivanan, N.; Johnston, L. J.; Wayner, D.D.M. Journal of Physical Chemistry, 1995 , vol. 99, # 20 p. 8190 - 8195

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被引用次数: 27

摘要

The radical anions of a series of substituted a-(ary1oxy) acetophenones have been generated by trapping the solvated electron produced by 355-nm laser-induced photoionization of 4, 4'-dimethoxystilbene in either acetonitrile or dimethylformamide (DMF). The radical anion of the parent ketone, a-phenoxyacetophenone, has A,,, at 500 nm and decays with a rate constant 7 x lo5 sI. This rate constant reflects the rate of P-cleavage to ...