Journal of Fluorine Chemistry

Sigmatropic isomerizations in 2-aza-allylic systems. Part X. Prototropic and chlorotropic rearrangements in fluoroalkyl-substituted 1, 3-dichloro-imines

PP Onys' ko, TV Kim, EI Kiseleva, AD Sinitsa

文献索引：Onys'ko, P. P.; Kim, T. V.; Kiseleva, E. I.; Sinitsa, A. D. Journal of Fluorine Chemistry, 1994 , vol. 69, # 3 p. 213 - 218

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被引用次数: 3

摘要

Abstract The photochemical chlorination of N-benzylimidoyl chlorides RC (CI)= NCH 2 Ph (R= CF 3, CFCI 2, C 3 F 7, t Bu, Ar) results in RC (CI)= NCH (CI) Ph or its mixture with isomeric RCCI 2 N= CHPh depending on the nature of the substituent R. 1, 3-Prototropic and 1, 3-chlorotropic rearrangements in the chlorination products have been observed and investigated.