Organometallics

Oxidative Addition and Reductive Elimination Reactions of trans-[Ir (PPh3) 2 (CO)(NC4H4)] and trans, cis-[Ir (PPh3) 2 (H) 2 (CO)(NC4H4)], Including NH Bond- …

MS Driver, JF Hartwig

文献索引：Driver, Michael S.; Hartwig, John F. Organometallics, 1998 , vol. 17, # 6 p. 1134 - 1143

全文：HTML全文

被引用次数: 14

摘要

An iridium (I) pyrrolyl complex based on Vaska's complex was prepared, and its reactions with alkyl and acyl halide, silanes, stannanes, boranes, and H2 were studied. The Ir (III) dihydrido pyrrolyl complexes underwent reductive elimination of pyrrole in high yield, and this reaction is an unusual example of NH bond-forming reductive elimination.