Tetrahedron

Distannane mediated reaction of N-acyliminium ion pools with alkyl halides. A chain mechanism involving radical addition followed by electron transfer

T Maruyama, S Suga, J Yoshida

文献索引：Maruyama, Tomokazu; Suga, Seiji; Yoshida, Jun-ichi Tetrahedron, 2006 , vol. 62, # 27 p. 6519 - 6525

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被引用次数: 27

摘要

Hexabutyldistannane was found to be an effective mediator allowing the reaction of N- acyliminium ion pools with alkyl halides. A chain mechanism involving the addition of an alkyl radical generated from an alkyl halide to an N-acyliminium ion followed by the one- electron reduction of the resulting radical-cation by distannane was proposed.