Tetrahedron letters

A formal insertion of dichlorocarbene into a C Ar S bond

P Müller, G Bernardinelli, N Pautex

文献索引：Mueller, Paul; Bernardinelli, Gerald; Pautex, Nicole Tetrahedron Letters, 1988 , vol. 29, # 46 p. 5877 - 5880

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被引用次数: 4

摘要

Abstract Reaction of phase transfer generated dichlorocarbene with 9- thiomethylphenanthrene (4) leads to 6 rather than the expected addition product 5. 6 is formally derived from a carbene insertion into the C, S bond. 13 C-labelling shows that the CH 3 group of 4 is lost during the reaction.