DFT and Experimental Studies of Perchlorate Ion Coordination in cis/trans??Copper (II) Complexes of Tetradentate Pyridyl Ligands

…, J Cruz, S Bernès, VM Ugalde??Salvdivar…

文献索引：Pandiyan, Thangarasu; Guadalupe, Hernandez J.; Cruz, Julian; Bernes, Sylvain; Ugalde-Salvdivar, Victor M.; Gonzalez, Ignacio European Journal of Inorganic Chemistry, 2008 , # 21 p. 3274 - 3285

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被引用次数: 9

摘要

Abstract Spectral and structural studies of N, N′-dimethyl-N, N′-bis (pyridin-2-ylmethyl)-1, 2-diaminoethane (L 1), N, N′-dimethyl-N, N′-bis (pyridin-2-ylmethyl)-1, 3-diaminopropane (L 2), and their copper (II) complexes were carried out by spectroscopic and DFT methods. The DFT results show that conventional and nonconventional H-bonds present in L 1 and L 2 influence the NMR chemical shifts at different pH values, which thus suggests that the ...