Structure− Property Investigations of Conjugated Thiophenes Fused onto a Dehydro [14] annulene Scaffold

MJ O'Connor, RB Yelle, LN Zakharov…

文献索引：O'Connor, Matthew J.; Yelle, Robert B.; Zakharov, Lev N.; Haley, Michael M. Journal of Organic Chemistry, 2008 , vol. 73, # 12 p. 4424 - 4432

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被引用次数: 14

摘要

A series of 12 thieno-fused macrocycles based on the dehydro [14] annulene framework have been prepared. Studies have focused on the optical and electronic properties of the dehydrobenzothieno [14] annulenes (DBTAs) and dehydrothieno [14] annulenes (DTAs) utilizing NMR spectroscopy, UV− vis spectrophotometry, electrochemistry, and DFT computations. X-ray crystal structures were also obtained for two of the macrocycles. The ...