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The Journal of Chemical Physics

Equilibrium composition of selenium vapor; the thermodynamics of the vaporization of HgSe, CdSe, and SrSe

J Berkowitz, WA Chupka

文献索引:Berkowitz, J.; Chupka, W. A. Journal of Chemical Physics, 1966 , vol. 45, p. 4289 - 4302

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被引用次数: 111

摘要

The vapor compositions of SrSe, CdSe, HgSe, hexagonal selenium, α??monoclinic selenium, and some mixed sulfur—selenium crystals have been studied by mass??spectrometric analysis. Dissociation energies of Se2 (71.2±2 kcal/mole) and SrSe (59.1±3 kcal/mole) were obtained. The heats and free energies of formation of the various Se n molecular species detected in the vapor are also given. There is no significant difference between the ...