... In an extension to alicyclic chemistry an analogous intermediate 25 has been postu- lated by Rozen and Brandlo in the reaction of l-iodo- adamantane (24) with fluorine en route to l-fluoro- adamantane ... 14) See: Sheldon, R. A.; Kochi, J. K. Organic Reactions; Dauben ... 2864 J. Org ...