Chemistry Letters

Synthesis of HOMSi Reagents by Pd/Cu-Catalyzed Silylation of Bromoarenes with Disilanes

…, K Shimizu, C Tsuruoka, T Komiyama, T Hiyama

文献索引：Minami, Yasunori; Shimizu, Kenta; Tsuruoka, Chisato; Komiyama, Takeshi; Hiyama, Tamejiro Chemistry Letters, 2014 , vol. 43, # 2 p. 201 - 203

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被引用次数: 5

摘要

Silylation of aryl bromides with disilanes of type {[2-(PG OCH 2) C 6 H 4] Me 2 Si} 2 (PG: protecting group) successfully takes place in the presence of a Pd/Ruphos or Davephos/CuI catalytic system to afford HOMSi reagents containing various functional groups in good yields. BisHOMSi reagents were also prepared directly from the corresponding arylene dibromides.