Reactivity of silyl monomers for the oxidative polymerization of phenylene units
M Bouachrine, JP Lere-Porte…
文献索引：Bouachrine, Mohammed; Lere-Porte, Jean-Pierre; Moreau, Joel J. E. Phosphorus, Sulfur and Silicon and Related Elements, 1999 , vol. 152, p. 265 - 278
Abstract Oxidative coupling of silyl monomers containing phenylene units was performed electrochemically and chemically using FeCl3 as oxidant. 2, 5-Trimethylsilyl-1, 4- dihexoxybenzene led to poly (2, 5-dihexoxyparaphenylene) with a degree of polymerization higher than the one obtained upon oxdative coupling of non silyl monomers. The coupling reaction was however moderately improved in the case of 3, 6-bis-dimethylsilyl (Nn- ...
