Tetrahedron

New acylnitroso compounds for the asymmetric oxyamination of dienes

…, SJ McCarthy, C Mineur, D Belotti, G Dive, L Ghosez

文献索引：Gouverneur; McCarthy; Mineur; Belotti; Dive; Ghosez Tetrahedron, 1998 , vol. 54, # 35 p. 10537 - 10554

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被引用次数: 24

摘要

a series of new enantiomerically pure acylnitroso compounds have been prepared and tested as dienophiles for the asymmetric oxyamination of dienes. Very high selectivities were obtained with acylnitroso compounds derived from diphenylmethoxymethyl pyrrolidine 2c, the C2-symmetric pyrrolidines 2d-e and camphorsultam 2f.