A new cyclam providing the first example unequivocally proven by X-ray crystallography of a pendent co-ordinated pyridyl group

E Kimura, T Koike, H Nada, Y Iitaka

文献索引：Kimura,Eiichi; Koike, Tohru; Nada, Hiroko; Iitaka, Yoichi Journal of the Chemical Society, Chemical Communications, 1986 , # 17 p. 1322 - 1323

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被引用次数: 1

摘要

A new class of 14-membered tetra-azamacrocycle (cyclam) functionalised with a pendent pyridine ligand is reported; the X-ray crystal structure of its NiII complex (7a) provides the first unequivocal example of co-ordination of the pyridyl side-arm to the centrally placed metal ion.