Tetrahedron letters

Oxidative decar☐ ylation of α-amino acids: A mild and efficient method for the generation ofN-acyliminium ions

A Boto, R Herna, E Sua

文献索引：Boto, Alicia; Hernandez, Rosendo; Suarez, Ernesto Tetrahedron Letters, 1999 , vol. 40, # 32 p. 5945 - 5948

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被引用次数: 32

摘要

The oxidative decar☐ ylation of α-amino acids using the system (diacetoxyiodo) benzene or iodosylbenzene and iodine proceeded smoothly at room temperature. The intermediacy of anN-acyliminium cation has been demonstrated through intermolecular and intramolecular trapping with nucleophiles.