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Structure of Cyclization Products of Substituted 2-Amino-N-(2-hydroxyethyl) benzamides

GF Field, WJ Zally, LH Sternbach

文献索引:Field,G.F. et al. Journal of Organic Chemistry, 1965 , vol. 30, p. 2098 - 2100

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被引用次数: 6

摘要

XIV xv prepared this compound by reduction with iron and acid. The samples produced by both methods were identical in every respect. Compound Va could be retosylated under mild conditions to give IV which indicates that no rearrangement had occurred during the detosylation step. Furthermore the infrared band at 1645 cm.-l (6.08 p, C= N) is present in both compounds. Hydrolysis of Va with dilute acid6 produced VI which has a strong band ...