Organic Syntheses by Means of Noble Metal Compounds. XIV. The Carbonylation of Cyclooctadienes

J Tsuji, S Hosaka, J Kiji, T Susuki

文献索引：Tsuji,J. et al. Bulletin of the Chemical Society of Japan, 1966 , vol. 39, p. 141 - 145

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被引用次数: 31

摘要

The 1, 5-cyclooctadiene-palladium chloride complex and carbon monoxide react in ethanol to form ethyl 4-cyclooctenecarboxylate. The carbonylation of 1, 5-cyclooctadiene catalyzed by palladium chloride has given ethyl 4-cyclooctenecarboxylate and cyclooctanedicarboxylate. It has been found that the monoester can be obtained selectively under certain conditions; the further carbonylation of the monoester gives the diester. ...