Syntheses, structural studies and spectroscopic characterisation of pyridyl–phthalimide complexes of fac-(CO) 3 Re I-diimines
FL Thorp-Greenwood, MP Coogan, AJ Hallett…
文献索引：Thorp-Greenwood, Flora L.; Coogan, Michael P.; Hallett, Andrew J.; Laye, Rebecca H.; Pope, Simon J.A. Journal of Organometallic Chemistry, 2009 , vol. 694, # 9-10 p. 1400 - 1406
The mono-dentate ligands, 3-aminomethyl-N-phthalimido-pyridine (L1) and 3-amino-N- phthalimido-pyridine (L2), were synthesised using a solvent-free melt method. These ligands were then used to access three pairs of functionalised luminescent ReI complexes of the generic type fac-{Re (CO) 3 (diimine)(Ln)}(BF4)[where diimine= 4, 4′-dimethyl-2, 2′- bipyridine (dmb); 2, 2′-bipyridine (bpy); 1, 10-phenanthroline (phen)]. X-ray ...
