Formation of polysubstituted 1, 2, 5, 6-tetrahydropyridines from the 4+ 2 cycloaddition reaction of bis (phenylsulfonyl) butadienes with aryl imines

…, Y Gareau, B Harrison, BH Norman

文献索引：Padwa, Albert; Gareau, Yves; Harrison, Brian; Norman, Bryan H. Journal of Organic Chemistry, 1991 , vol. 56, # 8 p. 2713 - 2720

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被引用次数: 48

摘要

2714 J. Org. Chem., Vol. 56, No. 8, 1991 Padwa et al. similar reaction conditions. In all cases, the cycloaddition afforded a single product corresponding to a rearranged cycloadduct. N-(1-Deuteriobenzylidene) benzylamine, when treated with diene 1, produced cycloadduct 5 where the deuterium was adjacent to the nitrogen atom. The cycloaddition did not occur with imines derived from aryl ketones.