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The generation and reactions of C, N-dianions of aromatic tosylhydrazones; ortho-N-dilithiated benzophenone tosylhydrazone

JT Sharp, CED Skinner

文献索引:Sharp, John T.; Skinner, Carol E. D. Tetrahedron Letters, 1986 , vol. 27, # 7 p. 869 - 872

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被引用次数: 20

摘要

Abstract The ortho, N-dilithiated derivative of the tosylhydrazone of benzophenone (5) has been generated by metal-halogen exchange at low temperature. A range of alkylation, silylation and acylation reactions are described together with further reactions leading to 1, 2- diacylbenzenes, phthalazines, 1, 3-diphenyl-isobenzofuran, and a 1, 2, 3-diazaborine.