The reductive cross-coupling of ketones and aldehydes to olefins by ditungsten hexaalkoxides

MH Chisholm, JA Klang

文献索引：Chisholm, Malcolm H.; Klang, Jeffrey A. Journal of the American Chemical Society, 1989 , vol. 111, # 6 p. 2324 - 2325

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被引用次数: 26

摘要

The McMurry reaction, that involves the use of a reagent prepared from the reduction of TiCI, with LiA1H4, is a well-established procedure for the reductive coupling of organic carbonyl- containing compounds to olefins.'Another procedure, developed by Sharpless and coworkers, involves a reagent prepared by the reaction between wc16 and n-BuLi. 2 The latter works best for substrates containing one aryl substituent. Both the McMurry and ...